MATERIAL SAFETY DATA SHEET
EQUILON MSDS: 60022E-02 01/04/99
XHVI MOTOR OIL
TELEPHONE NUMBER:
24 HOUR EMERGENCY ASSISTANCE GENERAL MSDS ASSISTANCE
EQUIVA SERVICES: 877-276-7283 877-276-7285
CHEMTREC: 800-424-9300
NAME AND ADDRESS
EQUILON ENTERPRISES LLC
PRODUCT STEWARDSHIP
P.O. BOX 674414
HOUSTON, TX 77267-4414
_______________________________________________________________________________
SECTION I NAME
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PRODUCT: XHVI MOTOR OIL
CHEM NAME: MIXTURE (SEE SECTION II-A)
CHEM FAMILY: PETROLEUM HYDROCARBON; MOTOR OIL
SHELL CODE: 50114
HEALTH HAZARD: 1 FIRE HAZARD: 1 REACTIVITY: 0
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SECTION II-A PRODUCT/INGREDIENT
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NO. COMPOSITION CAS NO. PERCENT
--- ----------- ------- -------
P XHVI MOTOR OIL
1 HYDROTREATED HEAVY PARAFFINIC DISTILLATE 64742-54-7 0-75
2 SOLVENT DEWAXED, HEAVY PARAFFINIC DISTILLATE 64742-65-0 0-75
3 HYDROTREATED SLACK WAX 92062-09-4 3-10
4 POLYMERIC ADDITIVES IN OIL MIXTURE 10-20
5 ADDITIVE CONTAINING: MIXTURE 10-15
5A ZINC DIALKYL DITHIOPHOSPHATE
5B CALCIUM ALKYL DITHIOPHOSPHATE
5C MAGNESIUM LONG-CHAIN ALKARYL SULFONATE
NFPA HAZARD RATING: HEALTH 0 FIRE 1 REACTIVITY 0
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SECTION II-B ACUTE TOXICITY DATA
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NO. ACUTE ORAL LD50 ACUTE DERMAL LD50 ACUTE INHALATION LC50
--- --------------- ----------------- ---------------------
P NOT AVAILABLE
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SECTION III HEALTH INFORMATION
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THE HEALTH EFFECTS NOTED BELOW ARE CONSISTENT WITH REQUIREMENTS UNDER THE OSHA
HAZARD COMMUNICATION STANDARD (29 CFR 1910.1200).
EYE CONTACT: LUBRICATING OILS ARE GENERALLY CONSIDERED NO MORE THAN MINIMALLY
IRRITATING TO THE EYES.
SKIN CONTACT: LUBRICATING OILS ARE GENERALLY CONSIDERED NO MORE THAN MILDLY
IRRITATING TO THE SKIN. PROLONGED AND REPEATED CONTACT MAY
RESULT IN VARIOUS SKIN DISORDERS SUCH AS DERMATITIS, FOLLICULITIS
OR OIL ACNE.
INHALATION: INHALATION OF VAPOR (GENERATED AT HIGH TEMPERATURES ONLY) OR OIL
MIST FROM THIS PRODUCT MAY RESULT IN MILD IRRITATION OF THE UPPER
RESPIRATORY TRACT.
INGESTION: LUBRICATING OILS ARE GENERALLY CONSIDERED NO MORE THAN SLIGHTLY
TOXIC IF SWALLOWED.
SIGNS AND SYMPTOMS: IRRITATION AS NOTED ABOVE.
AGGRAVATED MEDICAL CONDITIONS:
PREEXISTING SKIN AND RESPIRATORY DISORDERS MAY BE AGGRAVATED BY EXPOSURE TO
THIS PRODUCT.
OTHER HEALTH EFFECTS:
THE INTERNATIONAL AGENCY FOR RESEARCH ON CANCER HAS DETERMINED THERE IS
SUFFICIENT EVIDENCE FOR THE CARCINOGENICITY IN EXPERIMENTAL ANIMALS OF USED
MOTOR OILS. HANDLING PROCEDURES AND SAFETY PRECAUTIONS IN THE MSDS SHOULD BE
FOLLOWED TO MINIMIZE EMPLOYEE'S EXPOSURE TO THE USED PRODUCT.
SEE SECTION VI FOR ADDITIONAL HEALTH INFORMATION.
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SECTION IV OCCUPATIONAL EXPOSURE LIMITS
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COMP OSHA ACGIH
NO. PEL/TWA PEL/CEILING TLV/TWA TLV/STEL OTHER
--- ------- ----------- ------- -------- -----
P 5 MG/M3* NONE 5 MG/M3* 10 MG/M3*
*OIL MIST, MINERAL
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SECTION V EMERGENCY AND FIRST AID PROCEDURES
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EYE CONTACT: FLUSH WITH WATER FOR 15 MINUTES WHILE HOLDING EYELIDS OPEN. GET
MEDICAL ATTENTION.
SKIN CONTACT: REMOVE CONTAMINATED CLOTHING AND WIPE EXCESS OFF. WASH WITH SOAP
AND WATER OR A WATERLESS HAND CLEANER FOLLOWED BY SOAP AND WATER.
IF IRRITATION OCCURS, GET MEDICAL ATTENTION.
INHALATION: REMOVE VICTIM TO FRESH AIR AND PROVIDE OXYGEN IF BREATHING IS
DIFFICULT. GET MEDICAL ATTENTION.
INGESTION: DO NOT INDUCE VOMITING. IN GENERAL NO TREATMENT IS NECESSARY
UNLESS LARGE QUANTITIES OF PRODUCT ARE INGESTED. HOWEVER, GET
MEDICAL ATTENTION.
NOTE TO PHYSICIAN: IN GENERAL, EMESIS INDUCTION IS UNNECESSARY IN HIGH
VISCOSITY, LOW VOLATILITY PRODUCTS, I.E., MOST OILS AND
GREASES.
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SECTION VI SUPPLEMENTAL HEALTH INFORMATION
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SUPPLIER OF COMPONENT 5 REPORTS THE FOLLOWING: "EPA HAS BEEN NOTIFIED OF
SUBSTANTIAL RISK REPORTS UNDER TSCA SECTION 8(E) ON ZINC DITHIOPHOSPHATES BASED
ON RABBIT DERMAL STUDIES AND ON IN-VITRO MUTAGENIC STUDIES. STUDIES PERFORMED
AFTER THE NOTIFICATION INDICATE THAT ZINC DITHIOPHOSPHATES DO NOT APPEAR TO
PRESENT A SIGNIFICANT HEALTH RISK WHEN PROPER HYGIENE AND PERSONAL PROTECTION
PRECAUTIONS ARE FOLLOWED."
SUPPLIER OF COMPONENT 5 REPORTS THAT THE CALCIUM ALKYL DITHIOPHOSPHATE AND
THE MAGNESIUM LONG-CHAIN ALKARYL SULFONATE ARE DERMAL SENSITIZERS IN GUINEA
PIGS. HOWEVER, BASED ON TEST RESULTS AT END-USE CONCENTRATIONS, THE SUPPLIER
BELIEVES THAT THIS COMPONENT IS NOT A SENSITIZER IN FINISHED OIL.
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SECTION VII PHYSICAL DATA
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BOILING POINT (DEG F): SPECFIC GRAVITY (H2O = 1): VAPOR PRESSURE (MM HG):
NOT AVAILABLE 0.8735 <0.1
MELTING POINT (DEG F): SOLUBILITY IN WATER: VAPOR DENSITY (AIR = 1):
-35 (POUR POINT) NEGLIGIBLE NOT AVAILABLE
VISCOSITY: 10-12
(CS @ 212 DEG F)
EVAPORATION RATE (NORMAL BUTYL ACETATE = 1):NOT AVAILABLE
APPEARANCE AND ODOR:DARK RED LIQUID. SLIGHT HYDROCARBON ODOR.
PHYS/CHEM PROPERTIES: SEE ABOVE FOR DETAILS
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SECTION VIII FIRE AND EXPLOSION HAZARDS
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FLASH POINT AND METHOD: 365 DEG F (PMCC)
FLAMMABLE LIMITS/PERCENT VOLUME IN AIR: LOWER: N/AV HIGHER: N/AV
EXTINGUISHING MEDIA:
USE WATER FOG, FOAM, DRY CHEMICAL OR CO2. DO NOT USE A DIRECT STREAM OF
WATER. PRODUCT WILL FLOAT AND CAN BE REIGNITED ON SURFACE OF WATER.
SPECIAL FIRE FIGHTING PROCEDURES AND PRECAUTIONS:
MATERIAL WILL NOT BURN UNLESS PREHEATED. DO NOT ENTER CONFINED FIRE-SPACE
WITHOUT FULL BUNKER GEAR (HELMET WITH FACE SHIELD, BUNKER COATS, GLOVES AND
RUBBER BOOTS), INCLUDING A POSITIVE-PRESSURE NIOSH-APPROVED SELF-CONTAINED
BREATHING APPARATUS. COOL FIRE EXPOSED CONTAINERS WITH WATER.
UNUSUAL FIRE AND EXPLOSION HAZARDS:
NONE IDENTIFIED
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SECTION IX REACTIVITY
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STABLITY: STABLE HAZARDOUS POLYMERIZATION WILL NOT OCCUR
CONDITIONS AND MATERIALS TO AVOID:
AVOID HEAT, OPEN FLAMES AND OXIDIZING MATERIALS.
HAZARDOUS DECOMPOSITION PRODUCTS:
THERMAL DECOMPOSITION PRODUCTS ARE HIGHLY DEPENDENT ON THE COMBUSTION
CONDITIONS. A COMPLEX MIXTURE OF AIRBORNE SOLID, LIQUID, PARTICULATES AND
GASES WILL EVOLVE WHEN THIS MATERIAL UNDERGOES PYROLYSIS OR COMBUSTION.
CARBON MONOXIDE AND OTHER UNIDENTIFIED ORGANIC COMPOUNDS MAY BE FORMED UPON
COMBUSTION.
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SECTION X EMPLOYEE PROTECTION
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RESPIRATORY PROTECTION:
IF EXPOSURE MAY OR DOES EXCEED OCCUPATIONAL EXPOSURE LIMITS (SECTION IV) USE
A NIOSH-APPROVED RESPIRATOR TO PREVENT OVEREXPOSURE. IN ACCORD WITH 29 CFR
1910.134 USE EITHER AN ATMOSPHERE-SUPPLYING RESPIRATOR OR AN AIR-PURIFYING
RESPIRATOR FOR ORGANIC VAPORS AND PARTICULATES.
PROTECTIVE CLOTHING
WEAR CHEMICAL RESISTANT GLOVES AND OTHER PROTECTIVE CLOTHING AS REQUIRED TO
MINIMIZE SKIN CONTACT. WEAR SAFETY GOGGLES TO AVOID EYE CONTACT. TEST DATA
FROM PUBLISHED LITERATURE AND/OR GLOVE AND CLOTHING MANUFACTURERS INDICATE
THE BEST PROTECTION IS PROVIDED BY NITRILE GLOVES.
ADDITIONAL PROTECTIVE MEASURES:
NONE IDENTIFIED
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SECTION XI ENVIRONMENTAL PROTECTION
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SPILL OR LEAK PROCEDURES:
MAY BURN ALTHOUGH NO READILY IGNITABLE. USE CAUTIOUS JUDGMENT WHEN CLEANING
UP LARGE SPILLS. *** LARGE SPILLS *** WEAR RESPIRATOR AND PROTECTIVE
CLOTHING AS APPROPRIATE. SHUT OFF SOURCE OF LEAK IF SAFE TO DO SO. DIKE AND
CONTAIN. REMOVE WITH VACUUM TRUCKS OR PUMP TO STORAGE SALVAGE VESSELS. SOAK
UP RESIDUE WITH AN ABSORBENT SUCH AS CLAY, SAND, OR OTHER SUITABLE MATERIALS;
DISPOSE OF PROPERLY. FLUSH AREA WITH WATER TO REMOVE TRACE RESIDUE. ***
SMALL SPILLS *** TAKE UP WITH AN ABSORBENT MATERIAL AND DISPOSE OF PROPERLY.
_______________________________________________________________________________
SECTION XII SPECIAL PRECAUTIONS
_______________________________________________________________________________
MINIMIZE SKIN CONTACT. WASH WITH SOAP AND WATER BEFORE EATING, DRINKING,
SMOKING OR USING TOILET FACILITIES. LAUNDER CONTAMINATED CLOTHING BEFORE
REUSE. PROPERLY DISPOSE OF CONTAMINATED LEATHER ARTICLES, INCLUDING SHOES,
THAT CANNOT BE DECONTAMINATED.
STORE IN A COOL, DRY PLACE WITH ADEQUATE VENTILATION. KEEP AWAY FROM OPEN
FLAMES AND HIGH TEMPERATURES.
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SECTION XIII TRANSPORTATION REQUIREMENTS
_______________________________________________________________________________
DEPARTMENT OF TRANSPORTATION CLASSIFICATION:
NOT HAZARDOUS BY D.O.T. REGULATIONS
DOT PROPER SHIPPING NAME: NOT APPLICABLE
OTHER REQUIREMENTS: NOT APPLICABLE
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SECTION XIV OTHER REGULATORY CONTROLS
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THE COMPONENTS OF THIS PRODUCT ARE LISTED ON THE EPA/TSCA INVENTORY OF CHEMICAL
SUBSTANCES.
PROTECTION OF STRATOSPHERIC OZONE (PURSUANT TO SECTION 611 OF THE CLEAN AIR ACT
AMENDMENTS OF 1990): PER 40 CFR PART 82, THIS PRODUCT DOES NOT CONTAIN NOR
WAS IT DIRECTLY MANUFACTURED WITH ANY CLASS I OR CLASS II OZONE DEPLETING
SUBSTANCES.
IN ACCORDANCE WITH SARA TITLE III, SECTION 313, THE ATTACHED ENVIRONMENTAL DATA
SHEET (EDS) SHOULD ALWAYS BE COPIED AND SENT WITH THE MSDS.
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SECTION XV STATE REGULATORY INFORMATION
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STATE LISTED COMPONENT CAS NO PERCENT STATE CODE
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BASED ON INFORMATION AVAILABLE, THIS PRODUCT DOES NOT CONTAIN ANY
CHEMICAL SUBSTANCE LISTED ON A CHEMICAL SPECIFIC STATE LIST.
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SECTION XVI SPECIAL NOTES
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PRODUCT NAME CHANGE ONLY; FORMERLY SHELL FIRE & ICE(R) 200 5W/30 MOTOR OIL
XHVI.
_______________________________________________________________________________
THE INFORMATION CONTAINED IN THIS DATA SHEET IS BASED ON THE DATA AVAILABLE
TO US AT THIS TIME, AND IS BELIEVED TO BE ACCURATE BASED UPON THAT DATA. IT IS
PROVIDED INDEPENDENTLY OF ANY SALE OF THE PRODUCT, FOR PURPOSE OF HAZARD
COMMUNICATION. IT IS NOT INTENDED TO CONSTITUTE PRODUCT PERFORMANCE
INFORMATION, AND NO EXPRESS OR IMPLIED WARRANTY OF ANY KIND IS MADE WITH
RESPECT TO THE PRODUCT, UNDERLYING DATA OR THE INFORMATION CONTAINED
HEREIN. YOU ARE URGED TO OBTAIN DATA SHEETS FOR ALL PRODUCTS YOU BUY,
PROCESS, USE OR DISTRIBUTE, AND ARE ENCOURAGED TO ADVISE THOSE WHO MAY
COME IN CONTACT WITH SUCH PRODUCTS OF THE INFORMATION CONTAINED HEREIN.
TO DETERMINE THE APPLICABILITY OR EFFECT OF ANY LAW OR REGULATION WITH
RESPECT TO THE PRODUCT, YOU SHOULD CONSULT WITH YOUR LEGAL ADVISOR OR THE
APPROPRIATE GOVERNMENT AGENCY. WE WILL NOT PROVIDE ADVICE ON SUCH
MATTERS, OR BE RESPONSIBLE FOR ANY INJURY FROM THE USE OF THE PRODUCT
DESCRIBED HEREIN. THE UNDERLYING DATA, AND THE INFORMATION PROVIDED HEREIN
AS A RESULT OF THAT DATA, IS THE PROPERTY OF EQUIVA SERVICES, LLC AND IS NOT TO
BE THE SUBJECT OF SALE OR EXCHANGE WITHOUT THE EXPRESS WRITTEN CONSENT OF
EQUIVA SERVICES, LLC.
_______________________________________________________________________________
ENVIRONMENTAL DATA SHEET
EQUILON EDS: 60022E
XHVI MOTOR OIL
TELEPHONE NUMBER:
24 HOUR EMERGENCY ASSISTANCE GENERAL MSDS ASSISTANCE
EQUIVA SERVICES: 877-276-7283 877-276-7285
CHEMTREC: 800-424-9300
NAME AND ADDRESS
EQUILON ENTERPRISES
PRODUCT STEWARDSHIP
P.O. BOX 674414
HOUSTON, TX 77267-4414
PRODUCT CODE: 50114
_______________________________________________________________________________
SECTION I PRODUCT COMPOSITION
_______________________________________________________________________________
NO. COMPOSITION CAS PERCENT
===============================================================================
P XHVI MOTOR OIL MIXTURE 100
1 HYDROTREATED HEAVY PARAFFINIC DISTILLATE 64742-54-7 0-75
2 SOLVENT DEWAXED, HEAVY PARAFFINIC DISTIL 64742-65-0 0-75
LATE
3 HYDROTREATED SLACK WAX 92062-09-4 3-10
4 POLYMERIC ADDITIVES IN OIL MIXTURE 10-20
5 ADDITIVE CONTAINING: MIXTURE 10-15
5A ZINC DIALKYL DITHIOPHOSPHATE
5B CALCIUM ALKYL DITHIOPHOSPHATE
5C MAGNESIUM LONG-CHAIN ALKARYL SULFONAT
E
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SECTION II SARA TITLE III INFORMATION
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NO. EHS RQ EHS TPQ SEC-313 313 CATEGORY 311/312 CATEGORY
(*1) (*2) (*3) (*4) (*5)
===============================================================================
5A YES ZINC COMPOUNDS H-2
5B H-1
5C H-1
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*1 = REPORTABLE QUANTITY OF EXTREMELY HAZARDOUS SUBSTANCE, SEC 302
*2 = THRESHOLD PLANNING QUANTITY, EXTREMELY HAZARDOUS SUBSTANCE, SEC 302
*3 = TOXIC CHEMICAL, SEC 313
*4 = CATEGORY AS REQUIRED BY SEC 313 (40 CFR 372.65 C), MUST BE USED ON TOXIC
RELEASE INVENTORY FORM
*5 = CATEGORY (FOR AGGREGATE REPORTING REQUIREMENTS UNDER SARA 311, 312)
HEALTH: H-1 = IMMEDIATE (ACUTE) HEALTH HAZARD
H-2 = DELAYED (CHRONIC) HEALTH HAZARD
PHYSICAL: P-3 = FIRE HAZARD
P-4 = SUDDEN RELEASE OF PRESSURE HAZARD
P-5 = REACTIVE HAZARD
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SECTION III ENVIRONMENTAL RELEASE INFORMATION
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THIS PRODUCT IS COVERED BY EPA'S COMPREHENSIVE ENVIRONMENTAL RESPONSE,
COMPENSATION AND LIABILITY ACT (CERCLA) PETROLEUM EXCLUSION. THEREFORE
RELEASES TO AIR, LAND, OR WATER ARE NOT REPORTABLE UNDER CERCLA
("SUPERFUND"). HOWEVER UNDER SECTION 311 OF EPA'S CLEAN WATER ACT (CWA),
THIS PRODUCT IS CONSIDERED AN OIL. AS SUCH , SPILLS INTO OR LEADING TO
SURFACE WATERS THAT CAUSE A SHEEN MUST BE REPORTED TO THE NATIONAL RESPONSE
CENTER, 800-424-8802.
THIS PRODUCT IS AN OIL UNDER 49 CFR (DOT) PART 130. IF SHIPPED BY RAIL OR
HIGHWAY IN A TANK WITH A CAPACITY OF 3,500 GALLONS OR MORE, IT IS SUBJECT TO
THE REQUIREMENTS OF PART 130. MIXTURE SOLUTIONS IN WHICH THIS PRODUCT IS
PRESENT AT 10% OR MORE MAY ALSO BE SUBJECT TO THIS RULE.
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SECTION IV RCRA INFORMATION
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IF THIS PRODUCT BECOMES A WASTE, IT WOULD NOT BE A HAZARDOUS WASTE BY RCRA
CRITERIA (40 CFR 261). PLACE IN AN APPROPRIATE DISPOSAL FACILITY IN
COMPLIANCE WITH LOCAL REGULATIONS.
_______________________________________________________________________________
THE INFORMATION CONTAINED IN THIS DATA SHEET IS BASED ON THE DATA AVAILABLE
TO US AT THIS TIME, AND IS BELIEVED TO BE ACCURATE BASED UPON THAT DATA. IT IS
PROVIDED INDEPENDENTLY OF ANY SALE OF THE PRODUCT, FOR PURPOSE OF HAZARD
COMMUNICATION. IT IS NOT INTENDED TO CONSTITUTE PRODUCT PERFORMANCE
INFORMATION, AND NO EXPRESS OR IMPLIED WARRANTY OF ANY KIND IS MADE WITH
RESPECT TO THE PRODUCT, UNDERLYING DATA OR THE INFORMATION CONTAINED
HEREIN. YOU ARE URGED TO OBTAIN DATA SHEETS FOR ALL PRODUCTS YOU BUY,
PROCESS, USE OR DISTRIBUTE, AND ARE ENCOURAGED TO ADVISE THOSE WHO MAY
COME IN CONTACT WITH SUCH PRODUCTS OF THE INFORMATION CONTAINED HEREIN.
TO DETERMINE THE APPLICABILITY OR EFFECT OF ANY LAW OR REGULATION WITH
RESPECT TO THE PRODUCT, YOU SHOULD CONSULT WITH YOUR LEGAL ADVISOR OR THE
APPROPRIATE GOVERNMENT AGENCY. WE WILL NOT PROVIDE ADVICE ON SUCH
MATTERS, OR BE RESPONSIBLE FOR ANY INJURY FROM THE USE OF THE PRODUCT
DESCRIBED HEREIN. THE UNDERLYING DATA, AND THE INFORMATION PROVIDED HEREIN
AS A RESULT OF THAT DATA, IS THE PROPERTY OF EQUIVA SERVICES, LLC AND IS NOT TO
BE THE SUBJECT OF SALE OR EXCHANGE WITHOUT THE EXPRESS WRITTEN CONSENT OF
EQUIVA SERVICES, LLC.
_______________________________________________________________________________
KAREN G. HAYNES
---------------
EQUIVA SERVICES LLC
P.O. BOX 674414
HOUSTON, TX 77267-4414
FOR ADDITIONAL INFORMATION ON THIS ENVIRONMENTAL DATA PLEASE CALL
(877) 276-7285
FOR EMERGENCY ASSISTANCE PLEASE CALL
EQUIVA SERVICES LLC: (877) 276-7283
CHEMTREC: (800) 424-9300
}